Pracownia Odziaływań Międzymolekularnych

::dr hab. Wiktor Koźmiński::
   Office adress:
   Department of Chemistry
   Warsaw University
   PL-02-093 Warszawa, Pasteura 1 , e-mail: kozmin. at. chem.uw.edu.pl
   phone:+48 22-8-220-211 ext.219;fax +48 22 8225996 , room number: 156

Born:	14 May 1964, Warsaw
Citizenship:	Polish

Education:	1982-87	Student of Chemistry at Warsaw University M.Sc. June 1987.
	1993	Ph.D. Under the supervision of Prof. L. Stefaniak.
	2001	D.Sc. (habilitation) with honors, Chemistry Department of Warsaw University.
Professional	1987-1994	Institut of Organic Chemistry Polish Academy of Sciences, including Ph.D. Studies 1988-92.
	1994-1996	Postdoctoral fellow, Organisch-chemisches Institut der Universität Zürich in group of Prof. W. von Philipsborn.
	1996-present	Chemistry Department of Warsaw University.
	2005	extraordinary professor
Scientific interests:		Methodology of modern NMR spectroscopy and its applications in Chemistry and Biochemistry. Most important topics include: development of new pulse sequences for faster or more accurate determination of spectral parameters, methods of fast acquisition of multimensional spectra, determination of scalar and residual dipolar couplings, chiral recognition.

Honors:
		1.Stipend of the Foundation for Polish Science, 1993. 2. Wiktor Kemula Award, 2001. 3. Award of the Prime Minister of Poland, 2003.

List of Pubications:

60. Podstawowe techniki eksperymentalne spektroskopii NMR w fazie ciekłej W. Koźmiński,
Wiadomości Chemiczne, 59, 107-120, (2005)

59. Efficient compensation of low-frequency magnetic field disturbance in NMR with fluxgate sensors.
J. Magn. Reson.174, 287-291 (2005); Wiktor Koźmiński, K Kazimierczuk.

58. A protein backbone &Psi and &Phi angle dependence of ²JN_(i),C_&alpha(i-1): the new NMR experiment and quantum chemical calculations. W. Koźmiński, I. Zhukov, M. Pecul, J. Sadlej, J. Biomol. NMR, in press, (2005).

57. The set of triple-resonance sequences with a multiple quantum coherence evolution period W. Koźmiński, I. Zhukov, J.Magn. Reson, 171, 338-344 (2004).

56. The DQ-HN{CACB} and DQ-HN(CO){CACB} sequences with evolution of double quantum C_&alpha-C_&beta coherences W. Koźmiński, I. Zhukov, J. Magn. Reson., 171, 186-191 (2004).

55. ¹⁵N, ¹³C and ¹H nuclear magnetic shielding and spin-spin coupling in gaseous ¹⁵N-enriched methylamine. E. Wielogorska, W. Makulski, W. Kozminski, K. Jackowski, J. Mol. Struct, 704, 305-309 (2004).

54. ¹⁵NH₄⁺ ion motion inside d(G₄T₄G₄)₂ G-quadruplex is accelerated in the presence of smaller Na⁺ ions. Primož Šket, Martin Črnugelj, Wiktor Koźmiński, Janez Plavec, Org. Biomol. Chem., 2, 1970-1973 (2004).

53. A Study of Multiple Complexation of &alpha-, &beta- and &gamma-Cyclodextrins: Surprisingly Differing Stoichiometries of &beta- and &gamma-Cyclodextrin Complexes Helena Dodziuk, Oleg M. Demchuk, Anna Bielejewska, Wiktor Koźmiński, Grygoriy Dolgonos, Supramolecular Chem. 16, 287-292 (2004).

52. NMR Studies of Chiral Recognition by Cyclodextrins H. Dodziuk, W. Koźmiński, A. Ejchart, Chirality, 16, 90-105 (2004). (praca przeglądowa)

51. Multiple quadrature detection in reduced dimensionality experiments W. Koźmiński, I. Zhukov, J. Biomol. NMR, 26, 157-166, (2003).

50. 1:3 Complex between &beta-Cyclodextrin and Dendrimer with Three Branches Involving Four Glycine and One Adamantyl Group H. Dodziuk, O. Demchuk, W. Koźmiński, G. Dolgonos, Pol. J. Chem., 77, 333-340 (2003).

49. The new HMQC based technique for the quantitative determination of heteronuclear coupling constants. Application for the measurement of ³J(H3^'_i, P_i+1) in DNA oligomers. W. Koźmiński, E. Bednarek, W. Bocian, J. Sitkowski, L. Kozerski, J.Magn. Reson, 160, 120-125 (2003).

48. On the impossibility of determination of stepwise binding constants for the 1:2 complex of (+)-camphor with &alpha-cyclodextrin. H. Dodziuk, K. S. Nowiński, W. Koźmiński, G. Dolgonos, Org. Biomol. Chem., 1, 581-584 (2003).

47. Differences between the &Delta H and &Delta S values of the 1:2 complex of camphor enantiomers with &alpha-cyclodextrin determined by NMR titrations and by other techniques. H. Dodziuk, W. Koźmiński, G. Dolgonos, Pol. J. Chem., 77, 251-255 (2003).

46. The Tautomeric Equilibrium and Stereochenistry of &beta-Sulfonylenamines. L. Kozerski, B. Kwiecień, P. Krajewski, R. Kawęcki, E. Bednarek, J. Sitkowski, W. Bocian, W. Koźmiński, P.E. Hansen, New J. Chem., 26, 1060-1069 (2002).

45. An Improved ³³S Magnetic Shielding Scale from the Gas Phase Study of OCS. K. Jackowski, W. Makulski, W. Koźmiński, Magn. Res Chem., 40, 563-565 (2002).

44. ¹⁵N, ¹³C and ¹H Nuclear Magnetic Shielding and Spin-Spin coupling Constants of 1-¹³C, ¹⁵N- Enriched Acetonitrile in Gaseous Mixtures with SF₆ and CO₂. M. Wilczek, W. Koźmiński, K. Jackowski, Chem. Phys. Lett., 358, 263-270 (2002).

43. Effects of Intermolecular Interactions on ³³S Magnetic Shielding in Gaseous SF₆ K. Jackowski, M. Wilczek, W. Makulski, W. Koźmiński, J. Phys Chem. A, 106, 2829-2832 (2002).

42. An Experimental Test of C-N Bond Twisting in the TICT State: Syn-Anti Photoisomerization in 2-(N-Methyl-N-isopropylamino)-5-cyanopiridine. J. Dobkowski, J. Wójcik, W. Koźmiński, R. Kołos, J. Waluk, J. Michl, J. Am. Chem. Soc., 124, 2406-2407 (2002).

41. Quantitative Methods for the Accurate Determination of Spin-Spin Coupling Constants. Application to the Measurement of ¹J(¹⁵N-¹H) in Gaseous NH₃. W. Koźmiński, Molecular Physics Reports, 33, 25-28 (2001).

40. Application of the HECADE Method to the Measurement of Long-Range Heteronuclear ¹³C, ¹H Spin-Spin Coupling Constants in Tautomeric &beta-Sulfonylenamines. W. Koźmiński, E. Bednarek, W. Bocian, J. Sitkowski, P.E. Hansen, B. Kwiecień, L. Kozerski, Magn. Res. Chem., 38, 839 (2000).

39. A New Accordion Approach for the measurement of ¹³C-¹³C Coupling Constants without a priori estimation of their magnitudes. W. Koźmiński, Molecular Physics Reports, 29, 183 (2000).

38. ¹⁵N NMR and X-ray Diffractometry in Structural Studies of Macrocyclic Lactams Containing Pyridine Moiety. D.T. Gryko, A.Pęcak, W. Koźmiński, P. Piątek, J. Jurczak, Supramolecular Chem. 12, 229 (2000).

37. Application of Spatially Resolved NMR Spectroscopy for High Resolution Spectra of Heterogeneous Samples. W. Koźmiński. Pol. J. Chem., 74, 1185 (2000).

36. Application of Adiabatic Inversion Pulses for Elimination of Baseline Distortions in FT NMR. A Natural Abundance ¹⁷O NMR Spectrum for Gaseous Acetone. W. Koźmiński, K. Jackowski, Magn. Res. Chem., 38, 459 (2000).

35. NMR Manifestation and Molecular Modeling of Chiral Recognition of &alpha-Pinenes by &alpha-Cyclodextrin. H. Dodziuk, W. Koźmiński, O. Lukin, D. Sybilska, J. Mol. Struct., 523, 205 (2000).

34. A Dynamic NMR Study of Self-inclusion of the Pendant Group in Amphiphilic 6-Thiophenyl 1-6-deoxy-Cyclodextrins. H. Dodziuk, K.Chmurski, J. Jurczak, W. Koźmiński, O. Lukin, J. Sitkowski, L. Stefaniak, J. Mol. Struct., 519, 33 (2000).

33. Sensitivity Improvement and New Acquisition Scheme of Heteronuclear Active-Coupling-Pattern- Tilting Spectroscopy. W. Koźmiński, D. Nanz, J.Magn. Reson, 142, 294 (2000).

32. A Pure-Phase Homonuclear J-Modulated HMQC Experiment with Tilted Cross-Peak Patterns for an Accurate Determination of Homonuclear Coupling Constants. W. Koźmiński, J. Magn. Reson. 141, 185 (1999).

31. Rosavin as a product of the glycosylation by Rhodiola rosea (roseroot) cell cultures. M. Furmanowa, M. Hartwich, A.W. Alferman, W. Koźmiński, M. Olejnik, Plant Cell, Tiss. Org., 56, 105 (1999).

30. Simplified Multiplet Pattern HSQC-TOCSY Experiments for an Accurate Determination of Long-Range Heteronuclear Coupling Constants. W. Koźmiński, J. Magn. Reson, 137, 408 (1999).

29. The New Active-Coupling- Pattern Tilting Experiment for an Efficient and Accurate Determination of Homonuclear Coupling Constants. W. Koźmiński, J. Magn. Reson, 134, 189 (1998).

28. One-Bond ¹⁰³Rh, ¹⁵N Coupling Constants of Axial and Equatorial Ligands in Rhodoximes. G. Hopp Rentsch, W. Koźmiński, W. von Philipsborn, F. Asaro, G. Pellizer, Magn. Res. Chem., 35, 904 (1997).

27. Synthesis and Characterization of 1,2-Disubstituted Vinylsilanes with ³J (²⁹Si, ¹H) Coupling Constants, Aplication of a Novel Heteronuclear J-Resolved NMR Experiment. S. Bratovanov, W. Koźmiński, J. Fässler, Z. Molnar, D. Nanz, S. Bienz. Organometallics, 16, 3128 (1997).

26. Pure-Phase Homo- and Heteronuclear J Spectra with Tilted Cross Peaks for an Accurate Determination of Coupling Constants. W. Koźmiński, S. Bienz, S. Bratovanov, D. Nanz, J. Magn. Reson, 125, 193 (1997).

25. HECADE: HMQC- and HSQC- based 2D NMR Experiments for Accurate and Sensitive Determination of Heteronuclear Coupling Constants from E.COSY - Type Cross Peaks. W. Koźmiński, D. Nanz, J. Magn. Reson., 124, 383 (1997).

24. Transition Metal-NMR at 14.1 T with a Low-Frequency Three Channel Inverse Probehead. D. Nanz, A. Bell, W. Koźmiński, E.J. Meier, V. Tedesco, W. von Philipsborn, Bruker Report, 143, 29 (1996).

23. New NMR Experiments for the Determination of Long-Range Heteronuclear Spin-Coupling Constants. W. Koźmiński, D. Nanz, W. von Philipsborn, Chimia, 50, 346 (1996).

22. Sensitive Measurement and Unambiguous Assignment of Long-Range ¹³C, ¹³C Coupling Constants at Natural Isotope Abundance. W. Koźmiński, D. Nanz, J. Magn. Reson., Ser. A, 122, 245 (1996).

21. An Analysis of the Bonding Properties of Benz[a]azulene by X-ray, NMR and Computational Studies. M. Bühl, W. Koźmiński, A. Linden, D. Nanz, D. Sperandio and H.-J. Hansen, Helv. Chim. Acta, 79, 837 (1996).

20. ¹⁸⁷Os NMR Study of (&eta ⁶-Arene) osmium(II) Complexes: Separation of Electronic and Steric Ligand Effects. A.G. Bell, W. Koźmiński, A. Linden and W. von Philipsborn, Organometallics, 15, 3124 (1996).

19. ⁵⁷Fe NMR Study of Ligand Effects in Cyclopentadienyliron Complexes. E.J.M. Meier, W. Koźmiński, A.Linden, P. Lustenberger and W. von Philipsborn, Organometallics, 15, 2469 (1996).

18. Sensitive Measurement of One-Bond Carbon-Carbon Spin Coupling Constants at Natural Isotope Abundance. W. Koźmiński, D. Sperandio, D. Nanz, Magn. Res. Chem., 34, 311 (1996).

17. ⁵⁷Fe, ¹³C Coupling Constants from Inverse Detection Experiments on Natural Isotope Abundances. E.J.M. Meier, W. Koźmiński, W. von Philipsborn, Magn. Res. Chem., 34, 89 (1996).

16. Spin-Lattice Relaxation Times of Transition-Metal Nuclei From Inverse Detection Experiments. W. Koźmiński, W. von Philipsborn, J. Magn. Reson., Ser. A, 116, 262 (1995).

15. ¹⁵N and ¹³C solid - state nuclear magnetic resonance study of the 5-thiomethyltetrazole. W. Koźmiński, F. Aguilar-Parrilla, I. Wawer, H.-H. Limbach, L. Stefaniak, Solid State NMR, 4, 121 (1995).

14. ¹⁵N CP MAS NMR Study of 5-Aminotetrazole Monohydrate. W. Koźmiński, L. Stefaniak, J. W. Wiench, Pol. J. Chem., 69, 74 (1995).

13. An X-Ray Study of Some 2,3-Diphenyltetrazolium Salts. R. Luboradzki, J. Lipkowski, W. Koźmiński, L. Stefaniak, J. Chem. Cryst., 25, 29 (1995).

12. Characteristic coupling constants ¹J_{(¹³C-¹³C)} of some mesoionic methylides containing a diphenyltetrazolium ring. J. Jaźwiński, W. Koźmiński, L. Stefaniak, G. A. Webb, Spectr. Int. J., 12, 21 (1994).

11. ¹³C and ¹⁵N Study of Mesoionic Type A and Type B Tetrazoles with Four Nitrogen Atoms in the Exocyclic Group. W. Koźmiński, J. Jaźwiński, L. Stefaniak, G. A. Webb, Magn. Res. Chem., 32, 746 (1994).

10. A Nitrogen NMR Study of 2,2'-Dipirydyloketone. W. Koźmiński, J. Jaźwiński, L. Stefaniak, G. A. Webb, Pol. J. Chem., 68, 2143 (1994).

9. ¹⁴N and ¹⁵N NMR study of 2,1,3-thiadiazolium-5-olate and related compounds. W. Koźmiński, J. Jaźwiński, L. Stefaniak, G. A. Webb, J. Mol. Struct., 323, 177 (1994).

8. A Multinuclear NMR Study of Some Mesoionic 1,3-Dimethyltetrazoles, 1- and 2- Methyltetrazoles and Related Compounds. W. Bocian, J. Jaźwiński, W. Koźmiński, L. Stefaniak, G. A. Webb, J. Chem.. Soc., Perkin Trans.,2 , 1327 (1994).

7. Multinuclear Magnetic Resonance Study of Some Mesoionic 1,3-Diphenyltetrazoles with Various Exocyclic Groups. W. Bocian, J. Jaźwiński, W. Koźmiński, L. Stefaniak, G. A. Webb, Magn. Res. Chem., 32, 284 (1994).

6. ¹⁴N, ¹⁵N, ¹³C and ¹H NMR Study of Mesoionic Thiocarbonyl Ylides with a 2,3-Diphenyltetrazolium Ring. W. Koźmiński, J. Jaźwiński, L. Stefaniak, J. Mol. Struct., 295, 15, (1993).

5. ¹³C and ¹⁵N NMR Study of 2,3-Diphenyltetrazolium-1,2,3,4-tetrazolium-5-aminides. W. Koźmiński, J. Jaźwiński, L. Stefaniak, Magn. Res. Chem., 31, 200, (1993).

4. An X-ray Study of Some Mesoionic 2,3-Diphenyltetrazoles. R. Luboradzki, W. Koźmiński, L. Stefaniak, J. Cryst. Spectr. Res., 23, 133, (1993).

3. A ¹³C and ¹⁵N NMR Study of Some Mesoionic 4-Hydroksypyrazole Derivatives in Various Solvents. W. Koźmiński, J. Jaźwiński, L. Stefaniak, G. A. Webb, J. Mol. Struct., 243, 369, (1991).

2. A Multinuclear NMR Study on Some Cyclic Aminidines and Related Compounds. J. Jaźwiński, W. Koźmiński, L. Stefaniak, G. A. Webb, J. Mol. Struct., 243, 365 (1991).

1. ¹³C and ¹⁵N NMR Study of 2,3-Diphenyltetrazolium-5-olate and 5-thiolate. W. Koźmiński, J. Jaźwiński, L. Stefaniak, G. A. Webb, Magn. Res. Chem., 28, 1027 (1990).